Each of these words means "certainly," "assuredly," "beyond question." They stem from a Latin word meaning "to waver" and hence convey the idea of steadiness, of something not subject to question: "She is undoubtedly (or indubitably or doubtlessly) the kindest person on this block." These words are interchangeable, although indubitably is less often used because it sounds somewhat more formal and pretentious than the others. The adjective forms of these adverbs (undoubted, indubitable, doubtless) are more often used and are also interchangeable.
Dictionary of problem words and expressions. Harry Shaw. 1975.